Cellular pH in resting skeletal muscle is typically 7.15 (Harmer et.al. 2000, Sullivan et.al. 1994, Hermansen and Osnes 1972).
Cellular pH falls in exercise in proportion to the intensity of the exercise, with increased pCO2 (see Blood Gases) and increased lactic acid concentrations (see Lactic Acid) both contributing to the acidity.
Exercising to exhaustion decreases skeletal muscle pH to around 6.60 (Harmer et.al. 2000, Sullivan et.al. 1994, Hermansen and Osnes 1972). The acidity appears to be an important contributor to the perceived and real exhaustion.
We can use lactate, pH and pCO2 data to estimate skeletal muscle strong ion difference. The equation for pH as a function of pCO2 and SID must be solved for two different conditions.
pH = pK + log (SID / pCO2)
The pH and lactate data is from Harmer et.al (2000) and the pCO2 data is from Sun et.al. (2001).
7.20 = pK + log (SID / 46)
6.57 = pK + log ((SID - 26) / 90)
The calculated strong ion difference is 48 mEq/L. The calculated pK is 7.18.
Divide mMol/kG dry by 4.06 or 4.12 to get mMol/L.
Hermansen, L. and J.-B. Osnes. Blood and pH after maximal exercise in man. J. Appl. Physiol. 32:304-308, 1972.
Sullivan, M.J., B. Saltin, R. Negro-Vilar, B.D. Duscha and H.C. Charles. Skeletal muscle pH assessed by biochemical and 31P-MRS methods during exercise and recovery in men. J. Appl. Physiol. 77:2194-2200, 1994.
Sun, X.-G., J.E. Hansen, W.W. Stringer, H. Ting and K. Wasserman. Carbon dioxide pressure-concentration relationship in arterial and mixed venous blood during exercise. J. Appl. Physiol. 90:1798-1810, 2001.
updated 03-02-05